SYNTHESIS OF ALKYL 1-HYDROXY-2,3- DIOXABICYCLO[4.3.0]NONANE-6-CARBOXYLATES

Authors

  • Huỳnh Thanh Trúc Faculty of Chemistry, Dalat University , Viet Nam
  • Nguyễn Thị Tố Uyên Faculty of Chemistry, Dalat University
  • Nguyễn Văn Hạ Faculty of Chemistry, Dalat University , Viet Nam

DOI:

https://doi.org/10.37569/DalatUniversity.1.1,2,3,&4.171(2011)

Keywords:

Endoperoxides, Aerobic oxidation, Manganese(III) acetate, Alkyl 2- oxocyclopentanecarboxylates

Abstract

Alkyl 2-oxocyclopentanecarboxylates react with manganese(III) acetate dihydrate in the presence of 1,1-diarylethenes to afford alkyl 4,4-diaryl-1-hydroxy-2,3-dioxabicyclo[4.3.0]nonan-6-carboxylates in good yields.Substituents on aryl ring of the alkene do not have remarkable influence on the product yield. The
reaction mechanism is discussed.

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Published

30-09-2011

Issue

Volume 1, Issue 1, 2, 3 & 4 (2011) - [No 1, Old version]

Section

Natural Sciences and Technology

License

Copyright (c) 2011 Huỳnh Thanh Trúc, Nguyễn Thị Tố Uyên, Nguyễn Văn Hạ

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

How to Cite

Trúc, H. T., Uyên, N. T. T., & Hạ, N. V. (2011). SYNTHESIS OF ALKYL 1-HYDROXY-2,3- DIOXABICYCLO[4.3.0]NONANE-6-CARBOXYLATES. Dalat University Journal of Science, 1(1,2,3,&4), 91-95. https://doi.org/10.37569/DalatUniversity.1.1,2,3,&4.171(2011)