SYNTHESIS OF ALKYL 1-HYDROXY-2,3- DIOXABICYCLO[4.3.0]NONANE-6-CARBOXYLATES
DOI:
https://doi.org/10.37569/DalatUniversity.1.1,2,3,&4.171(2011)Keywords:
Endoperoxides, Aerobic oxidation, Manganese(III) acetate, Alkyl 2- oxocyclopentanecarboxylatesAbstract
Alkyl 2-oxocyclopentanecarboxylates react with manganese(III) acetate dihydrate in the presence of 1,1-diarylethenes to afford alkyl 4,4-diaryl-1-hydroxy-2,3-dioxabicyclo[4.3.0]nonan-6-carboxylates in good yields.Substituents on aryl ring of the alkene do not have remarkable influence on the product yield. The
reaction mechanism is discussed.
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Published
30-09-2011
Volume and Issues
Section
Natural Sciences and Technology
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Copyright (c) 2011 Huỳnh Thanh Trúc, Nguyễn Thị Tố Uyên, Nguyễn Văn Hạ

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
How to Cite
Trúc, H. T., Uyên, N. T. T., & Hạ, N. V. (2011). SYNTHESIS OF ALKYL 1-HYDROXY-2,3- DIOXABICYCLO[4.3.0]NONANE-6-CARBOXYLATES. Dalat University Journal of Science, 1(1,2,3,&4), 91-95. https://doi.org/10.37569/DalatUniversity.1.1,2,3,&4.171(2011)